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    2019-1-1 · Zirconia. Zirconia-based femoral heads were introduced in the 1980s in response to concerns about Al 2 O 3 femoral head fractures in total hip arthroplasty (THA). Pure ZrO 2 exists in three polymorphic (crystalline) forms: cubic (c), tetragonal (t) and monoclinic (m) phases.

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